CAS Number:
107-31-3
Sum Formula:
C2H4O2
Molar Mass:
60 g/mol
German Synonyms:
Methylformiat | Ameisensäuremethylester
English Synonyms:
Methyl formate | Formic acid methyl ester
EC Index Number:
607-014-00-1
EC Number:
203-481-7
Temperature Class:
T2
Explosion Group:
IIA
Disclaimer: The CLP/GHS classification is not regularly updated in Chemsafe. For up-to-date information, please use the ECHA database. ( https://echa.europa.eu/en/information-on-chemicals )
GHS Hazard and Category:
- Flam. Liq. 1: flammable liquids, category 1
- Acute Tox. 4: acute oral toxicity, category 4
- Acute Tox. 4: acute toxicity by inhalation, category 4
- Eye Irrit. 2: eye irritation, category 2
- STOT SE 3: Specific target organ toxicity following single exposure, category 3, respiratory tract irritation or narcotic effects
GHS Pictogram:
GHS Signal Word:
Danger
GHS Hazard Statement:
- H224: Extremely flammable liquid and vapour.
- H332: Harmful if inhaled.
- H302: Harmful if swallowed.
- H319: Causes serious eye irritation.
- H335: May cause respiratory irritation.
Antoine parameters
1
1987
Stephenson, R.M.; Malanowski, S.
6.22596 kPa
UTI: 137-1018-15044/0-39
Bibliographic data
| Author | Stephenson, R.M.; Malanowski, S. |
| Year | 1987 |
| Title | Handbook of The Thermodynamics of Organic Compounds |
| Publisher | Elsevier; New York, Amsterdam, London |
| Language | ENGL |
Boiling point
1
1941
Berger, H.
1013.25 hPa
32 °C
UTI: 15-1018-15032/0-39
| Line no | Boiling temperature | Pressure |
|---|---|---|
|
|
|
| 1 | 32 °C | 1013.25 hPa |
Bibliographic data
| Title | Brennbare Gase, Flüssigkeiten und feste Stoffe |
| Author | Berger, H. |
| Year | 1941 |
| Publisher | Edmund Stein u. Co. |
| Publisher City | Potsdam |
| Language | GERM |
2
1950
1013.25 hPa
32 °C
UTI: 1-1018-15015/0-39
| Line no | Boiling temperature | Pressure |
|---|---|---|
|
|
|
| 1 | 32 °C | 1013.25 hPa |
Bibliographic data
| Title | Loss Prevention Bulletin No. 36.10: Properties of Flammable Liquids, Gases and Solids |
| Year | 1950 |
| Journal Title | The Factory Mutual Engineering Division;Boston, Ma |
| Publisher | The Factory Mutual Engineering Division |
| Publisher City | Boston |
| Language | ENGL |
3
1951
Oehley, E.
1013.25 hPa
31.8 °C
UTI: 13-1018-15025/0-39
| Line no | Boiling temperature | Pressure |
|---|---|---|
|
|
|
| 1 | 31.8 °C | 1013.25 hPa |
Bibliographic data
| Title | Stoffdaten |
| Author | Oehley, E. |
| Year | 1951 |
| Publisher | Farbwerke Hoechst, Techn. Abt. Farben-Gruppe |
| Language | GERM |
4
1963
Nabert, K.; Schön, G.
1013.25 hPa
32 °C
UTI: 1000-1018-15065/0-39
| Line no | Boiling temperature | Pressure |
|---|---|---|
|
|
|
| 1 | 32 °C | 1013.25 hPa |
Bibliographic data
| Author | Nabert, K.; Schön, G. |
| Year | 1963 |
| Title | Sicherheitstechnische Kennzahlen brennbarer Gase und Dämpfe (mit 6. Nachtrag) |
| Publisher | Deutscher Eichverlag |
| Publisher City | Braunschweig |
| Abstract English | Safety values of about 1000 flammable gases and vapors: Explosion limits, ignition temperatures, flash points, explosion pressures. |
| Language | GERM |
Density
1
1941
Berger, H.
1013.25 hPa
20 °C
0.975 g/cm3
UTI: 15-1018-15033/0-39
| Line no | Density | Temperature | Pressure |
|---|---|---|---|
|
|
|
|
| 1 | 0.975 g/cm3 | 20 °C | 1013.25 hPa |
Bibliographic data
| Title | Brennbare Gase, Flüssigkeiten und feste Stoffe |
| Author | Berger, H. |
| Year | 1941 |
| Publisher | Edmund Stein u. Co. |
| Publisher City | Potsdam |
| Language | GERM |
2
1950
1013.25 hPa
20 °C
0.975 g/cm3
UTI: 1-1018-15016/0-39
| Line no | Density | Temperature | Pressure |
|---|---|---|---|
|
|
|
|
| 1 | 0.975 g/cm3 | 20 °C | 1013.25 hPa |
Bibliographic data
| Title | Loss Prevention Bulletin No. 36.10: Properties of Flammable Liquids, Gases and Solids |
| Year | 1950 |
| Journal Title | The Factory Mutual Engineering Division;Boston, Ma |
| Publisher | The Factory Mutual Engineering Division |
| Publisher City | Boston |
| Language | ENGL |
3
1951
Oehley, E.
0.95 g/cm3 ... 1.003 g/cm3
UTI: 13-1018-15026/0-39
| Line no | Density |
|---|---|
|
|
| 1 | 0.95 g/cm3 ... 1.003 g/cm3 |
Bibliographic data
| Title | Stoffdaten |
| Author | Oehley, E. |
| Year | 1951 |
| Publisher | Farbwerke Hoechst, Techn. Abt. Farben-Gruppe |
| Language | GERM |
4
1963
Nabert, K.; Schön, G.
1013.25 hPa
20 °C
0.97 g/cm3
UTI: 1000-1018-15066/0-39
| Line no | Density | Temperature | Pressure |
|---|---|---|---|
|
|
|
|
| 1 | 0.97 g/cm3 | 20 °C | 1013.25 hPa |
Bibliographic data
| Author | Nabert, K.; Schön, G. |
| Year | 1963 |
| Title | Sicherheitstechnische Kennzahlen brennbarer Gase und Dämpfe (mit 6. Nachtrag) |
| Publisher | Deutscher Eichverlag |
| Publisher City | Braunschweig |
| Abstract English | Safety values of about 1000 flammable gases and vapors: Explosion limits, ignition temperatures, flash points, explosion pressures. |
| Language | GERM |
Diffusion coefficient
1
1963
Nabert, K.; Schön, G.
20 °C
0.10 cm2/s
UTI: 1000-1018-15069/0-39
Bibliographic data
| Author | Nabert, K.; Schön, G. |
| Year | 1963 |
| Title | Sicherheitstechnische Kennzahlen brennbarer Gase und Dämpfe (mit 6. Nachtrag) |
| Publisher | Deutscher Eichverlag |
| Publisher City | Braunschweig |
| Abstract English | Safety values of about 1000 flammable gases and vapors: Explosion limits, ignition temperatures, flash points, explosion pressures. |
| Language | GERM |
Melting point
1
1941
Berger, H.
-100 °C
UTI: 15-1018-15031/0-39
2
1950
-100 °C
UTI: 1-1018-15014/0-39
| Line no | Melting temperature |
|---|---|
|
|
| 1 | -100 °C |
Bibliographic data
| Title | Loss Prevention Bulletin No. 36.10: Properties of Flammable Liquids, Gases and Solids |
| Year | 1950 |
| Journal Title | The Factory Mutual Engineering Division;Boston, Ma |
| Publisher | The Factory Mutual Engineering Division |
| Publisher City | Boston |
| Language | ENGL |
3
1951
Oehley, E.
-100 °C
UTI: 13-1018-15024/0-39
4
1963
Nabert, K.; Schön, G.
1013.25 hPa
-100 °C
UTI: 1000-1018-15070/0-39
Bibliographic data
| Author | Nabert, K.; Schön, G. |
| Year | 1963 |
| Title | Sicherheitstechnische Kennzahlen brennbarer Gase und Dämpfe (mit 6. Nachtrag) |
| Publisher | Deutscher Eichverlag |
| Publisher City | Braunschweig |
| Abstract English | Safety values of about 1000 flammable gases and vapors: Explosion limits, ignition temperatures, flash points, explosion pressures. |
| Language | GERM |
Relative gas density
1
1941
Berger, H.
2.07
UTI: 15-1018-15034/0-39
2
1950
2.07
UTI: 1-1018-15017/0-39
| Line no | Relative gas density |
|---|---|
|
|
| 1 | 2.07 |
Bibliographic data
| Title | Loss Prevention Bulletin No. 36.10: Properties of Flammable Liquids, Gases and Solids |
| Year | 1950 |
| Journal Title | The Factory Mutual Engineering Division;Boston, Ma |
| Publisher | The Factory Mutual Engineering Division |
| Publisher City | Boston |
| Language | ENGL |
3
1963
Nabert, K.; Schön, G.
2.07
UTI: 1000-1018-15067/0-39
| Line no | Relative gas density |
|---|---|
|
|
| 1 | 2.07 |
Bibliographic data
| Author | Nabert, K.; Schön, G. |
| Year | 1963 |
| Title | Sicherheitstechnische Kennzahlen brennbarer Gase und Dämpfe (mit 6. Nachtrag) |
| Publisher | Deutscher Eichverlag |
| Publisher City | Braunschweig |
| Abstract English | Safety values of about 1000 flammable gases and vapors: Explosion limits, ignition temperatures, flash points, explosion pressures. |
| Language | GERM |
4
1994
2.07
UTI: 16-1018-15039/0-39
Solubility in water
1
2009
Physikalisch-Technische Bundesanstalt (PTB)
20 °C
300 g/l
UTI: 228-1018-15061/0-39
| Line no | Solubility in water | Temperature |
|---|---|---|
|
|
|
| 1 | 300 g/l | 20 °C |
Bibliographic data
| Author | Physikalisch-Technische Bundesanstalt (PTB) |
| Year | 2009 |
| Title | Wasserlöslichkeit |
| Database | PTB |
| Publisher | Datenbank PTB-Lab. 3.43 |
| Language | GERM |
- The oxidizing agent is air with an oxygen content of 20.95 % by volume. In the data base it is usually not specified as mixture component. Exceptions are highlighted.
- Pressure values are absolute, not gauge pressures.
- Impurities can strongly influence characteristic safety data, particulary if the properties of the impurity considerably deviate from the respective properties of the pure substance.
- Safety characteristics are only displayed if evaluated data are available.
- Values can be cited by using the UTI number of the table (Uniform Table Identifier).
- Color Codes: recommended value no recommendation do not use value
Autoignition Temperature
1
1963
Nabert, K.; Schön, G.
450 °C
UTI: 1000-1018-15068/0-39
| Line no | Autoignition Temperature |
|---|---|
|
|
| 1 | 450 °C [A] |
| [A] DIN 51794: Testing of mineral oil hydrocarbons - Determination of ignition temperature; measurements are technically identical to those of ISO/IEC 80079-20-1 but results are treated differently. |
Bibliographic data
| Author | Nabert, K.; Schön, G. |
| Year | 1963 |
| Title | Sicherheitstechnische Kennzahlen brennbarer Gase und Dämpfe (mit 6. Nachtrag) |
| Publisher | Deutscher Eichverlag |
| Publisher City | Braunschweig |
| Abstract English | Safety values of about 1000 flammable gases and vapors: Explosion limits, ignition temperatures, flash points, explosion pressures. |
| Language | GERM |
2
1941
Berger, H.
449 °C
UTI: 15-1018-15038/0-39
| Line no | Autoignition Temperature |
|---|---|
|
|
| 1 | 449 °C |
Bibliographic data
| Title | Brennbare Gase, Flüssigkeiten und feste Stoffe |
| Author | Berger, H. |
| Year | 1941 |
| Publisher | Edmund Stein u. Co. |
| Publisher City | Potsdam |
| Language | GERM |
3
1948
Scott, G.S; Jones, G.W.; Scott, F.E.
236 °C
UTI: 26-1018-15042/0-39
| Line no | Autoignition Temperature |
|---|---|
|
|
| 1 | 236 °C |
Bibliographic data
| Title | Determination of Ignition Temperatures of Combustible Liquids and Gases |
| Author | Scott, G.S; Jones, G.W.; Scott, F.E. |
| Year | 1948 |
| Journal Title | Anal. Chem. |
| Volume | 20 |
| Issue | 3 |
| Pages | 238-241 |
| Publisher | Anal. Chem. |
| Language | ENGL |
4
1950
456 °C
UTI: 1-1018-15021/0-39
| Line no | Autoignition Temperature |
|---|---|
|
|
| 1 | 456 °C |
Bibliographic data
| Title | Loss Prevention Bulletin No. 36.10: Properties of Flammable Liquids, Gases and Solids |
| Year | 1950 |
| Journal Title | The Factory Mutual Engineering Division;Boston, Ma |
| Publisher | The Factory Mutual Engineering Division |
| Publisher City | Boston |
| Language | ENGL |
5
1951
Oehley, E.
449 °C
UTI: 13-1018-15030/0-39
6
1975
Yagyu, S.
450 °C
UTI: 179-1018-15046/0-39
| Line no | Autoignition Temperature |
|---|---|
|
|
| 1 | 450 °C [A] |
| [A] IEC 79-4: Method of Test for Ignition Temperature, Electrical Apparatus for Explosive G; Replaced by IEC-60079-20-1 in 1975 |
Bibliographic data
| Title | Data for Ignition Temperature(1st and 2nd) |
| Author | Yagyu, S. |
| Year | 1975 |
| Publisher | RIIS |
| Language | JAPN |
Flash point
1
2014
Physikalisch-Technische Bundesanstalt (PTB)
-27 °C
UTI: 4034-1018-60151/20240730-39
| Line no | Flash point |
|---|---|
|
|
| 1 | -27 °C |
Bibliographic data
| Author | Physikalisch-Technische Bundesanstalt (PTB) |
| Year | 2014 |
| Title | Sicherheitstechnische Kenngrößen: Messwerte 2014 des PTB-Laboratoriums 3.71 |
| Database | PTB |
| Publisher | PTB-Lab. 3.71 |
| Language | GERM |
2
1941
Berger, H.
-19 °C
UTI: 15-1018-15035/0-39
3
1946
Freytag, H.
< -30 °C
UTI: 6-1018-15022/0-39
| Line no | Flash point |
|---|---|
|
|
| 1 | < -30 °C |
Bibliographic data
| Title | Merkblatt über Kennzahlen brennbarer Gase und Dämpfe |
| Author | Freytag, H. |
| Year | 1946 |
| Publisher | Magistrat von Gross-Berlin, Abteilung für Arbeit, Hauptamt für Arbeitsschutz |
| Publisher City | Berlin |
| Language | GERM |
4
1946
Freytag, H.
-19 °C
UTI: 6-1018-15023/0-39
| Line no | Flash point |
|---|---|
|
|
| 1 | -19 °C [1] |
| [1] Measuring method doubtful |
Bibliographic data
| Title | Merkblatt über Kennzahlen brennbarer Gase und Dämpfe |
| Author | Freytag, H. |
| Year | 1946 |
| Publisher | Magistrat von Gross-Berlin, Abteilung für Arbeit, Hauptamt für Arbeitsschutz |
| Publisher City | Berlin |
| Language | GERM |
5
1950
-19 °C
UTI: 1-1018-15018/0-39
| Line no | Flash point |
|---|---|
|
|
| 1 | -19 °C |
Bibliographic data
| Title | Loss Prevention Bulletin No. 36.10: Properties of Flammable Liquids, Gases and Solids |
| Year | 1950 |
| Journal Title | The Factory Mutual Engineering Division;Boston, Ma |
| Publisher | The Factory Mutual Engineering Division |
| Publisher City | Boston |
| Language | ENGL |
6
1951
Oehley, E.
-19 °C
UTI: 13-1018-15027/0-39
7
1963
Nabert, K.; Schön, G.
< -20 °C
UTI: 1000-1018-15063/0-39
| Line no | Flash point |
|---|---|
|
|
| 1 | < -20 °C |
Bibliographic data
| Author | Nabert, K.; Schön, G. |
| Year | 1963 |
| Title | Sicherheitstechnische Kennzahlen brennbarer Gase und Dämpfe (mit 6. Nachtrag) |
| Publisher | Deutscher Eichverlag |
| Publisher City | Braunschweig |
| Abstract English | Safety values of about 1000 flammable gases and vapors: Explosion limits, ignition temperatures, flash points, explosion pressures. |
| Language | GERM |
Limiting value for flammability (Tci)
1
2008
Physikalisch-Technische Bundesanstalt (PTB)
8.1 Mol%
UTI: 232-1018-15062/0-39
| Line no | Limiting value for flammability (Tci) |
|---|---|
|
|
| 1 | 8.1 Mol% |
Bibliographic data
| Author | Physikalisch-Technische Bundesanstalt (PTB) |
| Year | 2008 |
| Title | Draft for the revision of ISO 10156 'Gas cylinders - Gas and gas mixture - Determination of fire potential and oxidizing ability' |
| Database | PTB |
| Publisher | Datenbank PTB-Lab. 3.43 |
| Language | ENGL |
Explosion limits
Lower explosion limit
1
1941
Berger, H.
5 Vol%
UTI: 15-1018-15036/0-39
2
1950
4.5 Vol%
UTI: 1-1018-15019/0-39
| Line no | Lower explosion limit |
|---|---|
|
|
| 1 | 4.5 Vol% |
Bibliographic data
| Title | Loss Prevention Bulletin No. 36.10: Properties of Flammable Liquids, Gases and Solids |
| Year | 1950 |
| Journal Title | The Factory Mutual Engineering Division;Boston, Ma |
| Publisher | The Factory Mutual Engineering Division |
| Publisher City | Boston |
| Language | ENGL |
3
1951
Oehley, E.
5 Vol%
UTI: 13-1018-15028/0-39
4
1952
Coward, H.F.; Jones, G.W.
5 Vol% ... 5.9 Vol%
UTI: 22-1018-15040/0-39
| Line no | Lower explosion limit |
|---|---|
|
|
| 1 | 5 Vol% |
| 2 | 5.9 Vol% |
Bibliographic data
| Title | Limits of Flammability of Gases and Vapours |
| Author | Coward, H.F.; Jones, G.W. |
| Year | 1952 |
| Publisher | United States Government Printing Office |
| Publisher City | Washington |
| Language | ENGL |
5
1963
Nabert, K.; Schön, G.
5 Vol% ... 5.9 Vol% ± 10 %
UTI: 1000-1018-15071/0-39
| Line no | Lower explosion limit |
|---|---|
|
|
| 1 | 5 Vol% ± 10 % |
| 2 | 5.9 Vol% ± 10 % |
| 3 | 120 g/m3 ± 10 % ⚠ |
| 4 | 145 g/m3 ± 10 % ⚠ |
| ⚠ The reference for the specification in g/m3 is the molar volume at 20 °C |
Bibliographic data
| Author | Nabert, K.; Schön, G. |
| Year | 1963 |
| Title | Sicherheitstechnische Kennzahlen brennbarer Gase und Dämpfe (mit 6. Nachtrag) |
| Publisher | Deutscher Eichverlag |
| Publisher City | Braunschweig |
| Abstract English | Safety values of about 1000 flammable gases and vapors: Explosion limits, ignition temperatures, flash points, explosion pressures. |
| Language | GERM |
Upper explosion limit
1
1941
Berger, H.
22.7 Vol%
UTI: 15-1018-15037/0-39
2
1950
20 Vol%
UTI: 1-1018-15020/0-39
| Line no | Upper explosion limit |
|---|---|
|
|
| 1 | 20 Vol% |
Bibliographic data
| Title | Loss Prevention Bulletin No. 36.10: Properties of Flammable Liquids, Gases and Solids |
| Year | 1950 |
| Journal Title | The Factory Mutual Engineering Division;Boston, Ma |
| Publisher | The Factory Mutual Engineering Division |
| Publisher City | Boston |
| Language | ENGL |
3
1951
Oehley, E.
22.7 Vol%
UTI: 13-1018-15029/0-39
4
1952
Coward, H.F.; Jones, G.W.
20 Vol% ... 23 Vol%
UTI: 22-1018-15041/0-39
| Line no | Upper explosion limit |
|---|---|
|
|
| 1 | 20 Vol% |
| 2 | 23 Vol% |
Bibliographic data
| Title | Limits of Flammability of Gases and Vapours |
| Author | Coward, H.F.; Jones, G.W. |
| Year | 1952 |
| Publisher | United States Government Printing Office |
| Publisher City | Washington |
| Language | ENGL |
5
1963
Nabert, K.; Schön, G.
20 Vol% ... 23 Vol% ± 5 %
UTI: 1000-1018-15072/0-39
| Line no | Upper explosion limit |
|---|---|
|
|
| 1 | 20 Vol% ± 5 % |
| 2 | 23 Vol% ± 5 % |
| 3 | 500 g/m3 ± 5 % ⚠ |
| 4 | 570 g/m3 ± 5 % ⚠ |
| ⚠ The reference for the specification in g/m3 is the molar volume at 20 °C |
Bibliographic data
| Author | Nabert, K.; Schön, G. |
| Year | 1963 |
| Title | Sicherheitstechnische Kennzahlen brennbarer Gase und Dämpfe (mit 6. Nachtrag) |
| Publisher | Deutscher Eichverlag |
| Publisher City | Braunschweig |
| Abstract English | Safety values of about 1000 flammable gases and vapors: Explosion limits, ignition temperatures, flash points, explosion pressures. |
| Language | GERM |
Maximum experimental safe gap
1
1992
Nabert, K.; Schön, G.; Redeker, T.
0.94 mm
UTI: 1050-1018-15073/0-39
| Line no | Maximum experimental safe gap |
|---|---|
|
|
| 1 | 0.94 mm |
Bibliographic data
| Author | Nabert, K.; Schön, G.; Redeker, T. |
| Year | 1992 |
| Title | Sicherheitstechnische Kenngrößen brennbarer Gase und Dämpfe |
| Publisher | Deutscher Eichverlag |
| Publisher City | Braunschweig |
| Language | GERM |
Stoichiometric fraction of combustible substance in mixture with air
1
2005
Physikalisch-Technische Bundesanstalt (PTB)
9.5 Mol%
UTI: 220-1018-15060/0-39
| Line no | Stoichiometric fraction of combustible substance in mixture with air |
|---|---|
|
|
| 1 | 9.5 Mol% |
Bibliographic data
| Author | Physikalisch-Technische Bundesanstalt (PTB) |
| Year | 2005 |
| Title | Berechnete molare stöchiometrische Brenngasanteile in Luft (c_stoech) |
| Database | PTB |
| Publisher | Datenbank PTB-Lab. 3.43 |
| Language | GERM |
Stoichiometric fraction of combustible substance in mixture with oxygen
1
2005
Physikalisch-Technische Bundesanstalt (PTB)
33.3 Mol%
UTI: 219-1018-15059/0-39
| Line no | Stoichiometric fraction of combustible substance in mixture with oxygen |
|---|---|
|
|
| 1 | 33.3 Mol% |
Bibliographic data
| Author | Physikalisch-Technische Bundesanstalt (PTB) |
| Year | 2005 |
| Title | Berechnete molare stöchiometrische Brenngasanteile in Sauerstoff |
| Database | PTB |
| Publisher | Datenbank PTB-Lab. 3.43 |
| Language | GERM |
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