Silane

Disclaimer: The CLP/GHS classification is not regularly updated in Chemsafe. For up-to-date information, please use the ECHA database. ( https://echa.europa.eu/en/information-on-chemicals )

Boiling point

1

1990

Britton, L.G.

-112 °C

UTI: 5550-000-001/20111005

UTI: 5550-000-001/20111005;

Line no	Molar mass	Boiling temperature	Melting temperature	Critical temperature	Critical pressure
	defined value property of pure substance	defined value at atmospheric pressure property of pure substance	defined value at atmospheric pressure property of pure substance	defined value property of pure substance	defined value property of pure substance
1	32.118 g/mol	-112 °C	-185 °C	-3.5 °C	48.5 bar

Bibliographic data

Title	Combustion Hazards of Silane And Its Chlorides
Author	Britton, L.G.
Year	1990
Journal Title	Plant/Operations Progress
Volume	9
Issue	1
Pages	16-38
Publisher	Plant/Operations Progress
Abstract English	This paper addresses the unusual combustion hazards of silane and its chlorides, comprising homologous chlorosilane series SiHnCl4-n. The literature of silane is briefly reviewed and new experimental data presented showing the effects of sudden releases into free air. New data are presented for ignition sensitivities and deflagration rates of chlorosilane mixtures with air. Specific hazardous reactions of this group of materials are described.
Abstract German	Dieser Artikel beschäftigt sich mit den Silanen und ihren Chlorids und ein Vergleich der homologen Serie SiHnCl4-n ist hier zu finden. Eine Literaturzusammenfassung und neue Messdaten sind hier angegeben . Neue experimentelle Daten sind hier zu Zündwilligkeit und Explosionskenngrößen von Chlorsilanen in Luft veröffentlicht. Spezielle gefährliche Reaktionen von diesen Stoffgruppen sind hier beschrieben.
ISBN / ISSN	0278-4513
DOI	https://doi.org/10.1002/prsb.720090107
Language	ENGL

2

2016

BAM

-112 °C

UTI: 5000-030-003/20111005

UTI: 5000-030-003/20111005;

Line no	Relative gas density	Boiling temperature	Molar mass
	defined value property of pure substance	defined value property of pure substance	defined value property of pure substance
1	1.12	-112 °C	32.118 g/mol

Bibliographic data

Year	2016
Title	Recommended Safety Characteristics and Classifications of Flammable Gases and Gas Mixtures
Database	BAM
Publisher	Datenbank BAM-Projekt CHEMSAFE
Language	GERM

Critical density

1

1980

Braker, William; Mossman, Allen L.

0.242 g/cm3

UTI: 5593-010-001/20111005

UTI: 5593-010-001/20111005;

Line no	Critical density
	defined value property of pure substance
1	0.242 g/cm3

Bibliographic data

Title	Matheson Gas Data Book
Author	Braker, William; Mossman, Allen L.
Year	1980
Publisher	Matheson
ISBN / ISSN	978-9992670378
Abstract English	Physical properties of gases.
Abstract German	Physikalische Eigenschaften von Gasen
	711
Language	ENGL

2

Critical Data

2016

BAM

0.242 g/cm3

UTI: 5000-030-002/20111005

Critical Data

UTI: 5000-030-002/20111005;

Line no	Critical temperature	Critical pressure	Critical density
	defined value property of pure substance	defined value property of pure substance	defined value property of pure substance
1	-3.5 °C	4840 kPa	0.242 g/cm3

Bibliographic data

Year	2016
Title	Recommended Safety Characteristics and Classifications of Flammable Gases and Gas Mixtures
Database	BAM
Publisher	Datenbank BAM-Projekt CHEMSAFE
Language	GERM

Critical point

1

1990

Britton, L.G.

-3.5 °C

UTI: 5550-000-001/20111005

UTI: 5550-000-001/20111005;

Line no	Molar mass	Boiling temperature	Melting temperature	Critical temperature	Critical pressure
	defined value property of pure substance	defined value at atmospheric pressure property of pure substance	defined value at atmospheric pressure property of pure substance	defined value property of pure substance	defined value property of pure substance
1	32.118 g/mol	-112 °C	-185 °C	-3.5 °C	48.5 bar

Bibliographic data

Title	Combustion Hazards of Silane And Its Chlorides
Author	Britton, L.G.
Year	1990
Journal Title	Plant/Operations Progress
Volume	9
Issue	1
Pages	16-38
Publisher	Plant/Operations Progress
Abstract English	This paper addresses the unusual combustion hazards of silane and its chlorides, comprising homologous chlorosilane series SiHnCl4-n. The literature of silane is briefly reviewed and new experimental data presented showing the effects of sudden releases into free air. New data are presented for ignition sensitivities and deflagration rates of chlorosilane mixtures with air. Specific hazardous reactions of this group of materials are described.
Abstract German	Dieser Artikel beschäftigt sich mit den Silanen und ihren Chlorids und ein Vergleich der homologen Serie SiHnCl4-n ist hier zu finden. Eine Literaturzusammenfassung und neue Messdaten sind hier angegeben . Neue experimentelle Daten sind hier zu Zündwilligkeit und Explosionskenngrößen von Chlorsilanen in Luft veröffentlicht. Spezielle gefährliche Reaktionen von diesen Stoffgruppen sind hier beschrieben.
ISBN / ISSN	0278-4513
DOI	https://doi.org/10.1002/prsb.720090107
Language	ENGL

2

2007

BAM

-3.5 °C

UTI: 5592-040-001/20111005

UTI: 5592-040-001/20111005;

Line no	Critical temperature
	defined value property of pure substance
1	-3.5 °C

Bibliographic data

Year	2007
Title	Gas Encyclopedia
Database	BAM
URL	https://encyclopedia.airliquide.com/
Language	ENGL

3

Critical Data

2016

BAM

-3.5 °C

UTI: 5000-030-002/20111005

Critical Data

UTI: 5000-030-002/20111005;

Line no	Critical temperature	Critical pressure	Critical density
	defined value property of pure substance	defined value property of pure substance	defined value property of pure substance
1	-3.5 °C	4840 kPa	0.242 g/cm3

Bibliographic data

Year	2016
Title	Recommended Safety Characteristics and Classifications of Flammable Gases and Gas Mixtures
Database	BAM
Publisher	Datenbank BAM-Projekt CHEMSAFE
Language	GERM

Density

1

1990

Britton, L.G.

1.013 bar

0 °C

1.44 g/L

UTI: 5550-000-002/20111005

UTI: 5550-000-002/20111005;

Line no	Temperature	Pressure	Density
	Parameter of the measurement property of pure substance	Parameter of the measurement property of pure substance	defined value property of pure substance
1	0 °C	1.013 bar	1.44 g/L

Bibliographic data

Title	Combustion Hazards of Silane And Its Chlorides
Author	Britton, L.G.
Year	1990
Journal Title	Plant/Operations Progress
Volume	9
Issue	1
Pages	16-38
Publisher	Plant/Operations Progress
Abstract English	This paper addresses the unusual combustion hazards of silane and its chlorides, comprising homologous chlorosilane series SiHnCl4-n. The literature of silane is briefly reviewed and new experimental data presented showing the effects of sudden releases into free air. New data are presented for ignition sensitivities and deflagration rates of chlorosilane mixtures with air. Specific hazardous reactions of this group of materials are described.
Abstract German	Dieser Artikel beschäftigt sich mit den Silanen und ihren Chlorids und ein Vergleich der homologen Serie SiHnCl4-n ist hier zu finden. Eine Literaturzusammenfassung und neue Messdaten sind hier angegeben . Neue experimentelle Daten sind hier zu Zündwilligkeit und Explosionskenngrößen von Chlorsilanen in Luft veröffentlicht. Spezielle gefährliche Reaktionen von diesen Stoffgruppen sind hier beschrieben.
ISBN / ISSN	0278-4513
DOI	https://doi.org/10.1002/prsb.720090107
Language	ENGL

2

2003

BAM

101.3 kPa

0 °C

1.443 kg/m3

UTI: 5560-079-001/20111005

UTI: 5560-079-001/20111005;

Line no	Temperature	Pressure	Density
	Parameter of the measurement property of pure substance	Parameter of the measurement property of pure substance	defined value property of pure substance
1	0 °C	101.3 kPa	1.443 kg/m3

Bibliographic data

Year	2003
Title	Gasatlas
Database	BAM
Language	GERM

3

2016

BAM

101.3 kPa

0 °C

1.443 kg/m3

UTI: 5016-064-001/20111005

UTI: 5016-064-001/20111005;

Line no	Temperature	Pressure	Density
	Parameter of the measurement property of pure substance	Parameter of the measurement property of pure substance	defined value property of pure substance
1	0 °C	101.3 kPa	1.443 kg/m3

Bibliographic data

Year	2016
Title	Recommended Densities of Pure Gases
Database	BAM
Language	GERM

Melting point

1

1990

Britton, L.G.

-185 °C

UTI: 5550-000-001/20111005

UTI: 5550-000-001/20111005;

Line no	Molar mass	Boiling temperature	Melting temperature	Critical temperature	Critical pressure
	defined value property of pure substance	defined value at atmospheric pressure property of pure substance	defined value at atmospheric pressure property of pure substance	defined value property of pure substance	defined value property of pure substance
1	32.118 g/mol	-112 °C	-185 °C	-3.5 °C	48.5 bar

Bibliographic data

Title	Combustion Hazards of Silane And Its Chlorides
Author	Britton, L.G.
Year	1990
Journal Title	Plant/Operations Progress
Volume	9
Issue	1
Pages	16-38
Publisher	Plant/Operations Progress
Abstract English	This paper addresses the unusual combustion hazards of silane and its chlorides, comprising homologous chlorosilane series SiHnCl4-n. The literature of silane is briefly reviewed and new experimental data presented showing the effects of sudden releases into free air. New data are presented for ignition sensitivities and deflagration rates of chlorosilane mixtures with air. Specific hazardous reactions of this group of materials are described.
Abstract German	Dieser Artikel beschäftigt sich mit den Silanen und ihren Chlorids und ein Vergleich der homologen Serie SiHnCl4-n ist hier zu finden. Eine Literaturzusammenfassung und neue Messdaten sind hier angegeben . Neue experimentelle Daten sind hier zu Zündwilligkeit und Explosionskenngrößen von Chlorsilanen in Luft veröffentlicht. Spezielle gefährliche Reaktionen von diesen Stoffgruppen sind hier beschrieben.
ISBN / ISSN	0278-4513
DOI	https://doi.org/10.1002/prsb.720090107
Language	ENGL

Molar mass

1

1990

Britton, L.G.

32.118 g/mol

UTI: 5550-000-001/20111005

UTI: 5550-000-001/20111005;

Line no	Molar mass	Boiling temperature	Melting temperature	Critical temperature	Critical pressure
	defined value property of pure substance	defined value at atmospheric pressure property of pure substance	defined value at atmospheric pressure property of pure substance	defined value property of pure substance	defined value property of pure substance
1	32.118 g/mol	-112 °C	-185 °C	-3.5 °C	48.5 bar

Bibliographic data

Title	Combustion Hazards of Silane And Its Chlorides
Author	Britton, L.G.
Year	1990
Journal Title	Plant/Operations Progress
Volume	9
Issue	1
Pages	16-38
Publisher	Plant/Operations Progress
Abstract English	This paper addresses the unusual combustion hazards of silane and its chlorides, comprising homologous chlorosilane series SiHnCl4-n. The literature of silane is briefly reviewed and new experimental data presented showing the effects of sudden releases into free air. New data are presented for ignition sensitivities and deflagration rates of chlorosilane mixtures with air. Specific hazardous reactions of this group of materials are described.
Abstract German	Dieser Artikel beschäftigt sich mit den Silanen und ihren Chlorids und ein Vergleich der homologen Serie SiHnCl4-n ist hier zu finden. Eine Literaturzusammenfassung und neue Messdaten sind hier angegeben . Neue experimentelle Daten sind hier zu Zündwilligkeit und Explosionskenngrößen von Chlorsilanen in Luft veröffentlicht. Spezielle gefährliche Reaktionen von diesen Stoffgruppen sind hier beschrieben.
ISBN / ISSN	0278-4513
DOI	https://doi.org/10.1002/prsb.720090107
Language	ENGL

2

2016

BAM

32.118 g/mol

UTI: 5000-030-003/20111005

UTI: 5000-030-003/20111005;

Line no	Relative gas density	Boiling temperature	Molar mass
	defined value property of pure substance	defined value property of pure substance	defined value property of pure substance
1	1.12	-112 °C	32.118 g/mol

Bibliographic data

Year	2016
Title	Recommended Safety Characteristics and Classifications of Flammable Gases and Gas Mixtures
Database	BAM
Publisher	Datenbank BAM-Projekt CHEMSAFE
Language	GERM

Relative gas density

1

2006

1.12

UTI: 5594-066-001/20111005

UTI: 5594-066-001/20111005;

Line no	Relative gas density
	defined value property of pure substance
1	1.12

Bibliographic data

Year	2006
Title	DIN EN ISO 14912 Gas analysis - Conversion of gas mixture composition data (ISO 14912 :2003) German version EN ISO 14912:2006
Institution	DIN,Deutsches Institut für Normung e.V.
Language	ENGL

2

2016

BAM

1.12

UTI: 5000-030-003/20111005

UTI: 5000-030-003/20111005;

Line no	Relative gas density	Boiling temperature	Molar mass
	defined value property of pure substance	defined value property of pure substance	defined value property of pure substance
1	1.12	-112 °C	32.118 g/mol

Bibliographic data

Year	2016
Title	Recommended Safety Characteristics and Classifications of Flammable Gases and Gas Mixtures
Database	BAM
Publisher	Datenbank BAM-Projekt CHEMSAFE
Language	GERM

Limiting value for flammability (Tci)

1

2016

BAM

1 Mol%

UTI: 5009-066-001/20111005

UTI: 5009-066-001/20111005;

Line no	Limiting value for flammability (Tci)
	recommended value EU-standard property of pure substance
1	1 Mol%

Bibliographic data

Year	2016
Title	Recommended Tci values of Gases for Determination of fire potential for the selection of cylinder valve outlets 4.6 Calculation method: ISO 10156:2008 (E) - Draft
Database	BAM
Publisher	Datenbank BAM-Projekt CHEMSAFE
Language	ENGL

2

2008

1 Mol%

UTI: 5537-066-001/20111005

UTI: 5537-066-001/20111005;

Line no	Limiting value for flammability (Tci)
	recommended value EU-standard property of pure substance
1	1 Mol%

Bibliographic data

Year	2008
Title	Draft for the revision of ISO 10156 "Gas cylinders – Gas and gas mixture – Determination of fire potential and oxidizing ability"
Subtitle	Table 2 —Tci and Li values of flammable gases and vapours
Publisher	ISO
Institution	ISO - International Organization for Standardization
Language	ENGL

Lower explosion limit

1

2016

BAM

19 g/m3

UTI: 5000-030-001/20111005

UTI: 5000-030-001/20111005;

Line no	Lower explosion limit	Lower explosion limit
	recommended value at atmospheric pressure and room temperature property of pure substance	recommended value at atmospheric pressure and room temperature property of pure substance
1	1.4 Vol%	19 g/m3 ⚠

⚠ The reference for the specification in g/m3 is the molar volume at 20 °C

Bibliographic data

Year	2016
Title	Recommended Safety Characteristics and Classifications of Flammable Gases and Gas Mixtures
Database	BAM
Publisher	Datenbank BAM-Projekt CHEMSAFE
Language	GERM

2

1990

Britton, L.G.

1.013 bar

20 °C

1.4 Mol%

UTI: 5550-000-003/20111005

UTI: 5550-000-003/20111005;

Line no	Temperature	Pressure	Lower explosion limit
	Parameter of the measurement property of pure substance	Parameter of the measurement property of pure substance	property of pure substance
1	20 °C	1.013 bar	1.4 Mol%

Bibliographic data

Title	Combustion Hazards of Silane And Its Chlorides
Author	Britton, L.G.
Year	1990
Journal Title	Plant/Operations Progress
Volume	9
Issue	1
Pages	16-38
Publisher	Plant/Operations Progress
Abstract English	This paper addresses the unusual combustion hazards of silane and its chlorides, comprising homologous chlorosilane series SiHnCl4-n. The literature of silane is briefly reviewed and new experimental data presented showing the effects of sudden releases into free air. New data are presented for ignition sensitivities and deflagration rates of chlorosilane mixtures with air. Specific hazardous reactions of this group of materials are described.
Abstract German	Dieser Artikel beschäftigt sich mit den Silanen und ihren Chlorids und ein Vergleich der homologen Serie SiHnCl4-n ist hier zu finden. Eine Literaturzusammenfassung und neue Messdaten sind hier angegeben . Neue experimentelle Daten sind hier zu Zündwilligkeit und Explosionskenngrößen von Chlorsilanen in Luft veröffentlicht. Spezielle gefährliche Reaktionen von diesen Stoffgruppen sind hier beschrieben.
ISBN / ISSN	0278-4513
DOI	https://doi.org/10.1002/prsb.720090107
Language	ENGL

3

2016

BAM

1.4 Vol%

UTI: 5000-030-001/20111005

UTI: 5000-030-001/20111005;

Line no	Lower explosion limit	Lower explosion limit
	recommended value at atmospheric pressure and room temperature property of pure substance	recommended value at atmospheric pressure and room temperature property of pure substance
1	1.4 Vol%	19 g/m3 ⚠

⚠ The reference for the specification in g/m3 is the molar volume at 20 °C

Bibliographic data

Year	2016
Title	Recommended Safety Characteristics and Classifications of Flammable Gases and Gas Mixtures
Database	BAM
Publisher	Datenbank BAM-Projekt CHEMSAFE
Language	GERM