CAS Number:
590-18-1
Sum Formula:
C4H8
German Synonyms:
cis-But-2-en | (Z)-2-Butylen | cis-1,2-Dimethylaethylen | cis-1,2-Dimethylethylen | cis-1,2-Dimethylaethen | cis-1,2-Dimethylethen | cis-Butylen-2 | cis-Buten-2 | cis-2-Butylen | cis-2-Buten | (Z)-2-Buten
English Synonyms:
cis-Butylene-2 | cis-Butene-2 | cis-1,2-Dimethylethylene | cis-2-Butylene | cis-2-Butene | (Z)-2-Butene
EC Index Number:
601-012-00-4
EC Number:
209-673-7
Properties:
flammable, gas
Explosion Group:
IIB
Disclaimer: The CLP/GHS classification is not regularly updated in Chemsafe. For up-to-date information, please use the ECHA database. ( https://echa.europa.eu/en/information-on-chemicals )
GHS Hazard and Category:
- Flam. Gas 1: flammable gases, category 1
- Press. Gas: Compressed gases
GHS Pictogram:
GHS Signal Word:
Danger
GHS Hazard Statement:
- H220: Extremely flammable gas.
Boiling point
1
1990
Nabert, K.; Schön, G.
4 °C
UTI: 5510-013-002/20180208
Bibliographic data
| Title | Sicherheitstechnische Kennzahlen brennbarer Gase und Dämpfe (with 6. Supplement) |
| Author | Nabert, K.; Schön, G. |
| Year | 1990 |
| Publisher | Deutscher Eichverlag;Braunschweig (Pub.) |
| Abstract English | Safety values of about 1000 flammable gases and vapors: Explosion limits, ignition temperatures, flash points, explosion pressures. |
| Abstract German | Sicherheitstechnische Kenngrößen von ca. 1000 Gasen und Dämpfen: Explosionsgrenzen, Zündtemperaturen, Flammpunkte, Explosionsdrücke. |
| Language | GERM |
2
2007
BAM
3.7 °C
UTI: 5592-002-001/20111005
| Line no | Boiling temperature |
|---|---|
|
|
| 1 | 3.7 °C |
Bibliographic data
| Year | 2007 |
| Title | Gas Encyclopedia |
| Database | BAM |
| URL | https://encyclopedia.airliquide.com/ |
| Language | ENGL |
Critical density
1
Critical Data
2016
BAM
0.239 g/cm3
UTI: 5000-027-003/20111005
Bibliographic data
| Year | 2016 |
| Title | Recommended Safety Characteristics and Classifications of Flammable Gases and Gas Mixtures |
| Database | BAM |
| Publisher | Datenbank BAM-Projekt CHEMSAFE |
| Language | GERM |
Critical point
1
1990
Nabert, K.; Schön, G.
162 °C
UTI: 5510-013-002/20180208
Bibliographic data
| Title | Sicherheitstechnische Kennzahlen brennbarer Gase und Dämpfe (with 6. Supplement) |
| Author | Nabert, K.; Schön, G. |
| Year | 1990 |
| Publisher | Deutscher Eichverlag;Braunschweig (Pub.) |
| Abstract English | Safety values of about 1000 flammable gases and vapors: Explosion limits, ignition temperatures, flash points, explosion pressures. |
| Abstract German | Sicherheitstechnische Kenngrößen von ca. 1000 Gasen und Dämpfen: Explosionsgrenzen, Zündtemperaturen, Flammpunkte, Explosionsdrücke. |
| Language | GERM |
2
Critical Data
2016
BAM
162.4 °C
UTI: 5000-027-003/20111005
Bibliographic data
| Year | 2016 |
| Title | Recommended Safety Characteristics and Classifications of Flammable Gases and Gas Mixtures |
| Database | BAM |
| Publisher | Datenbank BAM-Projekt CHEMSAFE |
| Language | GERM |
Density
1
2003
BAM
101.3 kPa
0 °C
2.582 kg/m3
UTI: 5560-016-001/20111005
| Line no | Temperature | Pressure | Density |
|---|---|---|---|
|
|
|
|
| 1 | 0 °C | 101.3 kPa | 2.582 kg/m3 |
Bibliographic data
| Year | 2003 |
| Title | Gasatlas |
| Database | BAM |
| Language | GERM |
2
2016
BAM
101.3 kPa
0 °C
2.582 kg/m3
UTI: 5016-001-001/20111005
| Line no | Temperature | Pressure | Density |
|---|---|---|---|
|
|
|
|
| 1 | 0 °C | 101.3 kPa | 2.582 kg/m3 |
Bibliographic data
| Year | 2016 |
| Title | Recommended Densities of Pure Gases |
| Database | BAM |
| Language | GERM |
Melting point
1
1990
Nabert, K.; Schön, G.
-139 °C
UTI: 5510-013-002/20180208
Bibliographic data
| Title | Sicherheitstechnische Kennzahlen brennbarer Gase und Dämpfe (with 6. Supplement) |
| Author | Nabert, K.; Schön, G. |
| Year | 1990 |
| Publisher | Deutscher Eichverlag;Braunschweig (Pub.) |
| Abstract English | Safety values of about 1000 flammable gases and vapors: Explosion limits, ignition temperatures, flash points, explosion pressures. |
| Abstract German | Sicherheitstechnische Kenngrößen von ca. 1000 Gasen und Dämpfen: Explosionsgrenzen, Zündtemperaturen, Flammpunkte, Explosionsdrücke. |
| Language | GERM |
Molar mass
1
1990
Nabert, K.; Schön, G.
56.1 g/mol
UTI: 5510-013-002/20180208
Bibliographic data
| Title | Sicherheitstechnische Kennzahlen brennbarer Gase und Dämpfe (with 6. Supplement) |
| Author | Nabert, K.; Schön, G. |
| Year | 1990 |
| Publisher | Deutscher Eichverlag;Braunschweig (Pub.) |
| Abstract English | Safety values of about 1000 flammable gases and vapors: Explosion limits, ignition temperatures, flash points, explosion pressures. |
| Abstract German | Sicherheitstechnische Kenngrößen von ca. 1000 Gasen und Dämpfen: Explosionsgrenzen, Zündtemperaturen, Flammpunkte, Explosionsdrücke. |
| Language | GERM |
Relative gas density
1
1990
Nabert, K.; Schön, G.
1.94
UTI: 5510-013-002/20180208
Bibliographic data
| Title | Sicherheitstechnische Kennzahlen brennbarer Gase und Dämpfe (with 6. Supplement) |
| Author | Nabert, K.; Schön, G. |
| Year | 1990 |
| Publisher | Deutscher Eichverlag;Braunschweig (Pub.) |
| Abstract English | Safety values of about 1000 flammable gases and vapors: Explosion limits, ignition temperatures, flash points, explosion pressures. |
| Abstract German | Sicherheitstechnische Kenngrößen von ca. 1000 Gasen und Dämpfen: Explosionsgrenzen, Zündtemperaturen, Flammpunkte, Explosionsdrücke. |
| Language | GERM |
2
2006
2
UTI: 5594-010-001/20111005
| Line no | Relative gas density |
|---|---|
|
|
| 1 | 2 |
Bibliographic data
| Year | 2006 |
| Title | DIN EN ISO 14912 Gas analysis - Conversion of gas mixture composition data (ISO 14912 :2003) German version EN ISO 14912:2006 |
| Institution | DIN,Deutsches Institut für Normung e.V. |
| Language | ENGL |
- The oxidizing agent is air with an oxygen content of 20.95 % by volume. In the data base it is usually not specified as mixture component. Exceptions are highlighted.
- Pressure values are absolute, not gauge pressures.
- Impurities can strongly influence characteristic safety data, particulary if the properties of the impurity considerably deviate from the respective properties of the pure substance.
- Safety characteristics are only displayed if evaluated data are available.
- Values can be cited by using the UTI number of the table (Uniform Table Identifier).
- Color Codes: recommended value no recommendation do not use value
Autoignition Temperature
1
1965
Zabetakis, M. G.
325 °C
UTI: 5511-025-001/20111005
Bibliographic data
| Title | Flammability Characteristics of Combustible Gases and Vapors (Bulletin 627) |
| Author | Zabetakis, M. G. |
| Year | 1965 |
| Abstract English | Summary of limits of flammability and ignition temperatures of individual gases and vapors in air at atmospheric pressure. Appendix A, Table A-1. Explosion ranges, limits of flammability, maximum oxygen contents, and other safety data of flammable gas mixtures. |
| Abstract German | Eine Zusammenstellung der Explosionsgrenzen und der Zündtemperaturen einiger brennbarer Gase und Dämpfe in Luft bei Atmosphärendruck; Appendix A, Tafel A-1. Explosionsbereiche, Explosionsgrenzen, maximale Sauerstoffanteile und andere sicherheitstechnische Kenngrößen von brennbaren Gasgemischen. |
| Document Number | Zabetakis |
| Institution | U.S. Bureau of Mines |
| URL | https://www.osti.gov/servlets/purl/7328370 |
| Publisher | United States Government Printing Office |
| Publisher City | Washington |
| Language | ENGL |
2
1984
325 °C
UTI: 5541-001-001/20111005
| Line no | Autoignition Temperature |
|---|---|
|
|
| 1 | 325 °C |
Bibliographic data
| Title | Fire Hazard Properties of Flammable Liquids, Gases, and Volatile Solids Table |
| Year | 1984 |
| Publisher | National Fire Protection Association |
| Publisher City | Quincy, MA |
| Pages | 9-95 |
| 96 | |
| Language | ENGL |
3
1985
Kuchta, J. M.
325 °C
UTI: 5513-008-001/20111005
Bibliographic data
| Title | Investigation of Fire and Explosion Accidents in the Chemical, Mining, and Fuel-Related Industries - A Manual (Bulletin 680) |
| Author | Kuchta, J. M. |
| Year | 1985 |
| Abstract English | Summary of explosion limits, flash points, ignition temperatures and chemical-physical data of liquid and gaseous compounds (gaseous combustion in air at atmospheric pressure); Appendix A |
| Abstract German | Zusammenstellung von Explosionsgrenzen, Flammpunkten, Zündtemperaturen und chemisch-physikalischen Daten von Flüssigkeiten und Gasen (Explosion in der Gasphase bei Atmosphärendruck); Appendix A |
| Document Number | DEDO-117 |
| Institution | U.S. Bureau of Mines |
| Publisher | United States Government Printing Office |
| Publisher City | Washington |
| Language | ENGL |
Limiting value for flammability (Tci)
1
2016
BAM
3.3 Mol%
UTI: 5009-040-001/20111005
| Line no | Limiting value for flammability (Tci) |
|---|---|
|
|
| 1 | 3.3 Mol% |
Bibliographic data
| Year | 2016 |
| Title | Recommended Tci values of Gases for Determination of fire potential for the selection of cylinder valve outlets 4.6 Calculation method: ISO 10156:2008 (E) - Draft |
| Database | BAM |
| Publisher | Datenbank BAM-Projekt CHEMSAFE |
| Language | ENGL |
2
2008
3.3 Mol%
UTI: 5537-040-001/20111005
| Line no | Limiting value for flammability (Tci) |
|---|---|
|
|
| 1 | 3.3 Mol% |
Bibliographic data
| Year | 2008 |
| Title | Draft for the revision of ISO 10156 "Gas cylinders – Gas and gas mixture – Determination of fire potential and oxidizing ability" |
| Subtitle | Table 2 —Tci and Li values of flammable gases and vapours |
| Publisher | ISO |
| Institution | ISO - International Organization for Standardization |
| Language | ENGL |
Explosion limits
Lower explosion limit
1
2016
BAM
1.6 Vol%
UTI: 5000-027-001/20111005
Bibliographic data
| Year | 2016 |
| Title | Recommended Safety Characteristics and Classifications of Flammable Gases and Gas Mixtures |
| Database | BAM |
| Publisher | Datenbank BAM-Projekt CHEMSAFE |
| Language | GERM |
2
1952
Coward, H. F.; Jones, G. W.
1.8 Vol%
UTI: 5512-018-001/20111005
| Line no | Lower explosion limit | Upper explosion limit |
|---|---|---|
|
|
|
| 1 | 1.8 Vol% [1] | 9.7 Vol% [1] |
| [1] Upward propagation of flame in large vessels, open at their lower ends. |
Bibliographic data
| Title | Limits of Flammability of Gases and Vapors (Bulletin 503) |
| Author | Coward, H. F.; Jones, G. W. |
| Year | 1952 |
| Abstract English | Explosion limits of individual gases in air, oxygen and nitrous oxide. |
| Abstract German | Explosionsgrenzen von reinen Gasen in Luft, Sauerstoff und Distickstoffoxid. |
| Document Number | Coward/Jon |
| Institution | U.S. Bureau of Mines |
| Publisher | United States Government Printing Office |
| Publisher City | Washington |
| Language | ENGL |
3
1965
Zabetakis, M. G.
1.7 Vol%
UTI: 5511-025-001/20111005
Bibliographic data
| Title | Flammability Characteristics of Combustible Gases and Vapors (Bulletin 627) |
| Author | Zabetakis, M. G. |
| Year | 1965 |
| Abstract English | Summary of limits of flammability and ignition temperatures of individual gases and vapors in air at atmospheric pressure. Appendix A, Table A-1. Explosion ranges, limits of flammability, maximum oxygen contents, and other safety data of flammable gas mixtures. |
| Abstract German | Eine Zusammenstellung der Explosionsgrenzen und der Zündtemperaturen einiger brennbarer Gase und Dämpfe in Luft bei Atmosphärendruck; Appendix A, Tafel A-1. Explosionsbereiche, Explosionsgrenzen, maximale Sauerstoffanteile und andere sicherheitstechnische Kenngrößen von brennbaren Gasgemischen. |
| Document Number | Zabetakis |
| Institution | U.S. Bureau of Mines |
| URL | https://www.osti.gov/servlets/purl/7328370 |
| Publisher | United States Government Printing Office |
| Publisher City | Washington |
| Language | ENGL |
4
1985
Kuchta, J. M.
1.7 Vol%
UTI: 5513-008-001/20111005
Bibliographic data
| Title | Investigation of Fire and Explosion Accidents in the Chemical, Mining, and Fuel-Related Industries - A Manual (Bulletin 680) |
| Author | Kuchta, J. M. |
| Year | 1985 |
| Abstract English | Summary of explosion limits, flash points, ignition temperatures and chemical-physical data of liquid and gaseous compounds (gaseous combustion in air at atmospheric pressure); Appendix A |
| Abstract German | Zusammenstellung von Explosionsgrenzen, Flammpunkten, Zündtemperaturen und chemisch-physikalischen Daten von Flüssigkeiten und Gasen (Explosion in der Gasphase bei Atmosphärendruck); Appendix A |
| Document Number | DEDO-117 |
| Institution | U.S. Bureau of Mines |
| Publisher | United States Government Printing Office |
| Publisher City | Washington |
| Language | ENGL |
5
1990
Nabert, K.; Schön, G.
37 g/m3 ± 10 %
UTI: 5510-013-001/20111005
| ⚠ The reference for the specification in g/m3 is the molar volume at 20 °C |
Bibliographic data
| Title | Sicherheitstechnische Kennzahlen brennbarer Gase und Dämpfe (with 6. Supplement) |
| Author | Nabert, K.; Schön, G. |
| Year | 1990 |
| Publisher | Deutscher Eichverlag;Braunschweig (Pub.) |
| Abstract English | Safety values of about 1000 flammable gases and vapors: Explosion limits, ignition temperatures, flash points, explosion pressures. |
| Abstract German | Sicherheitstechnische Kenngrößen von ca. 1000 Gasen und Dämpfen: Explosionsgrenzen, Zündtemperaturen, Flammpunkte, Explosionsdrücke. |
| Language | GERM |
6
1990
Nabert, K.; Schön, G.
1.6 Vol% ± 10 %
UTI: 5510-013-001/20111005
| ⚠ The reference for the specification in g/m3 is the molar volume at 20 °C |
Bibliographic data
| Title | Sicherheitstechnische Kennzahlen brennbarer Gase und Dämpfe (with 6. Supplement) |
| Author | Nabert, K.; Schön, G. |
| Year | 1990 |
| Publisher | Deutscher Eichverlag;Braunschweig (Pub.) |
| Abstract English | Safety values of about 1000 flammable gases and vapors: Explosion limits, ignition temperatures, flash points, explosion pressures. |
| Abstract German | Sicherheitstechnische Kenngrößen von ca. 1000 Gasen und Dämpfen: Explosionsgrenzen, Zündtemperaturen, Flammpunkte, Explosionsdrücke. |
| Language | GERM |
Upper explosion limit
1
2016
BAM
10 Vol%
UTI: 5000-027-001/20111005
Bibliographic data
| Year | 2016 |
| Title | Recommended Safety Characteristics and Classifications of Flammable Gases and Gas Mixtures |
| Database | BAM |
| Publisher | Datenbank BAM-Projekt CHEMSAFE |
| Language | GERM |
2
1952
Coward, H. F.; Jones, G. W.
9.7 Vol%
UTI: 5512-018-001/20111005
| Line no | Lower explosion limit | Upper explosion limit |
|---|---|---|
|
|
|
| 1 | 1.8 Vol% [1] | 9.7 Vol% [1] |
| [1] Upward propagation of flame in large vessels, open at their lower ends. |
Bibliographic data
| Title | Limits of Flammability of Gases and Vapors (Bulletin 503) |
| Author | Coward, H. F.; Jones, G. W. |
| Year | 1952 |
| Abstract English | Explosion limits of individual gases in air, oxygen and nitrous oxide. |
| Abstract German | Explosionsgrenzen von reinen Gasen in Luft, Sauerstoff und Distickstoffoxid. |
| Document Number | Coward/Jon |
| Institution | U.S. Bureau of Mines |
| Publisher | United States Government Printing Office |
| Publisher City | Washington |
| Language | ENGL |
3
1965
Zabetakis, M. G.
9.7 Vol%
UTI: 5511-025-001/20111005
Bibliographic data
| Title | Flammability Characteristics of Combustible Gases and Vapors (Bulletin 627) |
| Author | Zabetakis, M. G. |
| Year | 1965 |
| Abstract English | Summary of limits of flammability and ignition temperatures of individual gases and vapors in air at atmospheric pressure. Appendix A, Table A-1. Explosion ranges, limits of flammability, maximum oxygen contents, and other safety data of flammable gas mixtures. |
| Abstract German | Eine Zusammenstellung der Explosionsgrenzen und der Zündtemperaturen einiger brennbarer Gase und Dämpfe in Luft bei Atmosphärendruck; Appendix A, Tafel A-1. Explosionsbereiche, Explosionsgrenzen, maximale Sauerstoffanteile und andere sicherheitstechnische Kenngrößen von brennbaren Gasgemischen. |
| Document Number | Zabetakis |
| Institution | U.S. Bureau of Mines |
| URL | https://www.osti.gov/servlets/purl/7328370 |
| Publisher | United States Government Printing Office |
| Publisher City | Washington |
| Language | ENGL |
4
1985
Kuchta, J. M.
9.7 Vol%
UTI: 5513-008-001/20111005
Bibliographic data
| Title | Investigation of Fire and Explosion Accidents in the Chemical, Mining, and Fuel-Related Industries - A Manual (Bulletin 680) |
| Author | Kuchta, J. M. |
| Year | 1985 |
| Abstract English | Summary of explosion limits, flash points, ignition temperatures and chemical-physical data of liquid and gaseous compounds (gaseous combustion in air at atmospheric pressure); Appendix A |
| Abstract German | Zusammenstellung von Explosionsgrenzen, Flammpunkten, Zündtemperaturen und chemisch-physikalischen Daten von Flüssigkeiten und Gasen (Explosion in der Gasphase bei Atmosphärendruck); Appendix A |
| Document Number | DEDO-117 |
| Institution | U.S. Bureau of Mines |
| Publisher | United States Government Printing Office |
| Publisher City | Washington |
| Language | ENGL |
5
1990
Nabert, K.; Schön, G.
235 g/m3 ± 5 %
UTI: 5510-013-001/20111005
| ⚠ The reference for the specification in g/m3 is the molar volume at 20 °C |
Bibliographic data
| Title | Sicherheitstechnische Kennzahlen brennbarer Gase und Dämpfe (with 6. Supplement) |
| Author | Nabert, K.; Schön, G. |
| Year | 1990 |
| Publisher | Deutscher Eichverlag;Braunschweig (Pub.) |
| Abstract English | Safety values of about 1000 flammable gases and vapors: Explosion limits, ignition temperatures, flash points, explosion pressures. |
| Abstract German | Sicherheitstechnische Kenngrößen von ca. 1000 Gasen und Dämpfen: Explosionsgrenzen, Zündtemperaturen, Flammpunkte, Explosionsdrücke. |
| Language | GERM |
6
1990
Nabert, K.; Schön, G.
10 Vol% ± 5 %
UTI: 5510-013-001/20111005
| ⚠ The reference for the specification in g/m3 is the molar volume at 20 °C |
Bibliographic data
| Title | Sicherheitstechnische Kennzahlen brennbarer Gase und Dämpfe (with 6. Supplement) |
| Author | Nabert, K.; Schön, G. |
| Year | 1990 |
| Publisher | Deutscher Eichverlag;Braunschweig (Pub.) |
| Abstract English | Safety values of about 1000 flammable gases and vapors: Explosion limits, ignition temperatures, flash points, explosion pressures. |
| Abstract German | Sicherheitstechnische Kenngrößen von ca. 1000 Gasen und Dämpfen: Explosionsgrenzen, Zündtemperaturen, Flammpunkte, Explosionsdrücke. |
| Language | GERM |
Maximum experimental safe gap
1
2016
BAM
0.89 mm
UTI: 5000-027-001/20111005
Bibliographic data
| Year | 2016 |
| Title | Recommended Safety Characteristics and Classifications of Flammable Gases and Gas Mixtures |
| Database | BAM |
| Publisher | Datenbank BAM-Projekt CHEMSAFE |
| Language | GERM |
Stoichiometric fraction of combustible substance in mixture with air
1
2016
BAM
3.4 Mol%
UTI: 5000-027-001/20111005
Bibliographic data
| Year | 2016 |
| Title | Recommended Safety Characteristics and Classifications of Flammable Gases and Gas Mixtures |
| Database | BAM |
| Publisher | Datenbank BAM-Projekt CHEMSAFE |
| Language | GERM |
Stoichiometric fraction of combustible substance in mixture with oxygen
1
2016
BAM
14.3 Mol%
UTI: 5000-027-001/20111005
Bibliographic data
| Year | 2016 |
| Title | Recommended Safety Characteristics and Classifications of Flammable Gases and Gas Mixtures |
| Database | BAM |
| Publisher | Datenbank BAM-Projekt CHEMSAFE |
| Language | GERM |
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- GESTIS
- BAM Dangerous Goods Database